姓名:董奎勇
系所:化学系
职称:副教授
个人简介:
董奎勇,1989年7月生,副教授,理学博士,2021年6月毕业于苏州大学获理学博士学位(导师:徐新芳教授)。近年来在Nat. Commun., Angew. Chem. Int. Ed., ACS Catal., Org.Lett., Chem. Com.等权威期刊发表SCI研究论文20余篇。
研究领域:
1.过渡金属催化及其不对称反应研究;
2.功能杂环化合物的不对称合成研究。
教育背景:
2017年9月—2021年6月:苏州大学材料与化学化工学部博士研究生;
2018年10月—2021年5月:美国德克萨斯大学圣安东尼奥分校化学系联合培养博士
2012年9月—2015年6月:苏州大学药学院硕士研究生;
2008年9月—2012年6月:皖南医学院药学系本科生。
主讲课程:
本科生:《有机化学实验》;《有机合成与综合实验》
科研项目:
1. 共催化策略高效构建手性吲哚杂环骨架,江苏省高校自然科学研究面上项目(22KJB150002),5万,2022.07-2024.06。
主要论文:
1. Kuiyong Dong*,Mengting Liu andXinfang Xu* Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates. Molecules2022, 27, 3088-3133.
2. Kuiyong Dong, Raj Gurung, Xinfang Xu* and Michael P. Doyle* Enantioselective Catalytic Cyclopropanation–Rearrangement Approach to Chiral Spiroketals. Org. Lett. 2021, 23, 3955-3959.
3. Kuiyong Dong, Ahmad Humeidi, Wendell Griffith, Hadi Arman, Xinfang Xu* and Michael P. Doyle* AgI-Catalyzed Reaction of Enol Diazoacetates and Imino Ethers: Synthesis of Highly Functionalized Pyrroles. Angew. Chem. Int. Ed. 2021, 60, 13394-13400.
4. Kuiyong Dong, Haifeng Zheng, Yongliang Su, Ahmad Humeidi, Hadi Arman, Xinfang Xu* and Michael P. Doyle* Catalyst-Directed Divergent Catalytic Approaches to Expand Structural and Functional Scaffold Diversity via Metallo-Enolcarbene Intermediates. ACS Catal. 2021, 11, 4712-4721.
5. Kuiyong Dong, Xinfang Xu* and Michael P. Doyle* Copper(I)-catalyzed highly enantioselective [3 + 3]-cycloaddition of γ-alkyl enoldiazoacetates with nitrones. Org. Chem. Front. 2020, 7, 1653-1657.
6. Kuiyong Dong, Xing Fan, Chao Pei, Yang Zheng, Sailan Chang, Ju Cai, Lihua Qiu, Zhi-Xiang Yu *and Xinfang Xu* Transient-axial-chirality controlled asymmetric rhodium-carbene C(sp2)-H functionalization for the synthesis of chiral fluorenes. Nat. Commun.,2020, 11, 2363.
7. Kuiyong Dong, Kostiantyn O. Marichev, and Michael P. Doyle* Role of Donor−Acceptor Cyclopropenes in Metal Carbene Reactions.Conversion of E‑Substituted Enoldiazoacetates to Z‑Substituted Metallo-Enolcarbenes. Organometallics2019, 38, 4043-4050.
8. Kuiyong Dong, Kostiantyn O. Marichev , Xingfang Xu* and Michael P. Doyle* High Stereocontrol in the Preparation of Silyl-Protected γ-Substituted Enoldiazoacetates. Synlett. 2019, 30, 1457-1461.
9. Kuiyong Dong, Chao Pei, Qian Zeng, Lihua Qiu, Wenhao Hu, Yu Qian and Xinfang Xu* Copper-catalyzed [4+1]-annulation of 2-alkenylindoles with diazoacetates: a facile access to dihydrocyclopenta[b]indoles. Chem. Commun. 2019, 55, 6393-6396.
10. Kuiyong Dong, Chao Pei, Qian Zeng, Hanlin Wei, Michael P. Doyle* and Xinfang Xu* Selective C(sp3)–H Bond Insertion in Carbene/Alkyne Metathesis Reactions. Enantioselective Construction of Dihydroindoles. ACS Catal. 2018, 8, 9543-9549.