姓名：李团结

系所：化学系

职称：教授

个人简介：

李团结，江苏丰县人，理学博士，教授，硕士生导师。近年来的研究内容主要集中在功能杂化的绿色合成、过渡金属催化的C-H键官能化和有机小分子催化等有机合成领域，已经发表论文三十多篇，主持或参与自然科学基金项目6项，先后获得校“先进工作者”、“就业工作促进先进个人”、“毕业论文优秀指导教师”等荣誉称号。

研究领域：

1. 功能杂环的绿色合成；

2. 金属催化的C-H键官能化；

3. 有机小分子催化。

教育背景：

2015/03 - 2016/03，斯克里普斯研究所(The Scripps Research Institute)，化学系，访问学者，有机化学；

2005/09 - 2008/06，南京大学，化学ylzzcom永利总站线路检测，博士研究生，生物无机化学；

2002/09 - 2005/06，徐州师范大学，化学系，硕士研究生，有机化学；

1991/09 -1995/06：徐州师范大学，化学系，本科生，化学教育。

主讲课程：

本科生：《无机化学》，《无机化学实验》，《配位化学》

科研项目：

1. 国家自然科学基金面上项目(21772070)，2017年-2021年，57万，主持人, 在研；

2. 江苏省高校自然科学研究重大项目(17KJA150003)，2017年-2019年，30万，主持人,已结题；

3. 徐州市自然科学基金（XM12B074），10万，主持人，已结题；

4. 江苏省高校自然科学研究重大项目（11KJA430009），第一参与人，已结题；

5. 国家自然科学基金专项基金 (21242014)，第一参与人，已结题；

6. 国家自然科学基金面上项目 (21372101，21271091)，第二参与人，已结题。

主要论文：

1. Wenchao Wu, Shuangli Xu, Yan Zhang, Xiu Wang, Ruotong Li, Fang Sun, Chenxia Yu, Tuanjie Li,^* Donghui Wei ^* and Changsheng Yao,^* NHC-catalyzed β-specific addition of N-based nucleophiles to allenoates,Org. Chem. Front., 2020, 7, 1593.

2. Fang Sun, Tingrui Yin, Yang Wang, Anni Feng, Liuqing Yang, Wenchao Wu, Chenxia Yu, Tuanjie Li,^* Donghui Wei^* and Changsheng Yao,^* A combined experimental and computational study of NHC-promoted desulfonylation of tosylated aldimines,Org. Chem. Front., 2020, 7, 578.

3. Li Cheng, Yuqian Sun, Wenrong Wang, Changsheng Yao^*, Tuan-Jie Li^*, ''Ligand-Free Copper(I)-Catalyzed Benzylic Acyloxylation of 2-Alkylpyridines under Aerobic Conditions”, J. Org. Chem.,2019, 84, 3074.

4. Yi-Feng Wang, Wen-Gang Xu, Bing Sun, Qin-Qin Yu, Tuan-Jie Li^*, Fang-Lin Zhang^*, “Monodentate Transient Directing Group Assisted Pd-Catalyzed Direct Dehydrogenative Cross-Coupling of Benzaldehydes with Arenes toward 9‑Fluorenones”, J. Org. Chem., 2019, 84, 13104.

5. Zhanlin Wang, Huiqing Zhang, Huimin Qian, Yuanfeng Wang, Chenxia Yu, Tuanjie Li^*, Changsheng Yao^*, “An NHC-catalyzed, stereoselective α-functionalization of α,β-unsaturated carboxylic acids through in-situ activation”, Org. Biomol. Chem., 2019, 17, 4564.

6. Fang Sun, Tingrui Yin, Anni Feng, Yong Hu, Chenxia Yu, Tuanjie Li^*, Changsheng Yao^*, “Base-promoted regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman carbonates by tuning the catalyst”, Org. Biomol. Chem., 2019, 17, 5283.

7. Yong Hu, Di Pan, Lin Cong, Yibiao Yao, Chenxia Yu, Tuanjie Li^*, and Changsheng Yao^*, “NHC-Catalyzed Efficient Syntheses of Isoquinolinones or Isochromanones through Formal [4+2] Cycloaddition of o-Quinodimethanes with Acylhydrazones or Ketones”,ChemistrySelect, 2018, 3, 1708.

8. Fang-Lin Zhang^*, Kai Hong^*, Tuan-Jie Li^*, Hojoon Park and Jin-Quan Yu, ''Functionalization of C(sp³)-H bonds using a transient directing group'',Science, 2016, 351, 252.

9. Yanyan Jia, Tuan-jie Li ^*, Chenxia Yu, Bo Jiang, Changsheng Yao, ^* ''A facile one-pot synthesis of 2,3-diarylated benzo[b]furans via relay NHC and palladium catalysis'', Org. Biomol. Chem., 2016, 14, 1982.

10. Guolin Cheng, Tuan-jie Li and Jin-Quan Yu^*,''Practical Pd(II)-catalyzed C-H Alkylation with Epoxides: One-step Syntheses of 3,4-Dihydroisocoumarins'', J. Am. Chem. Soc., 2015, 137, 10950.

11. Yonglei Que, Yuanwei Xie, Tuan-jie Li, Chenxia Yu, Shujiang Tu, Changsheng Yao^*, ''An N-Heterocyclic Carbene-Catalyzed Oxidative γ-Aminoalkylation of Saturated Carboxylic Acids through in Situ Activation Strategy: Access to δ-Lactam'', Org. Lett., 2015, 17, 6234.

12. Yonglei Que, Tuan-jie Li, Chenxia Yu, Xiang-Shan Wang, Changsheng Yao^*, ''Enantioselective Assembly of Spirocyclic Oxindole-dihydropyranones through NHC-Catalyzed Cascade Reaction of Isatins with N-Hydroxybenzotriazole Esters of α,β-Unsaturated Carboxylic Acid'',J. Org. Chem., 2015, 80, 3289.

13. Tuanjie Li, Ting Lu, Chenxia Yu, Changsheng Yao, '' An efficient synthesis of [1,3]dioxolo[4,5-g]thieno[3,4-b]quinolin-8(5H)-ones as novel thiazapodophyllotoxin analogues with potential anticancer activity'', Bioorg. Med. Chem. Lett., 2015, 25, 1417.

14. Zhaoxin Xiao, Chenxia Yu, Tuanjie Li, Xiang-Shan Wang, Changsheng Yao, ''N-Heterocyclic carbene/lewis acid strategy for the stereoselective synthesis of spirocyclic oxindole-dihydropyranones'', Org. Lett., 2014, 16, 3632.

15. Tuan-Jie Li, Zhong-Qiu Liu, Hong-Mei Yin, Chang-Sheng Yao, Bo Jiang, Xiang-Shan Wang,Shu-Jiang Tu, Xiu-Ling Li, Guigen Li, ''Metal-free [3 + 2 + 1]/[2 + 2 + 1] biscyclization: stereospecific construction with concomitant functionalization of indolizin-5(1H)-one'', J. Org. Chem., 2013, 78, 11414.

16. Tuan-Jie Li, Hong-Mei Yin, Chang-Sheng Yao, Xiang-Shan Wang, Bo Jiang, Shu-Jiang Tu, Guigen Li, ''A one-pot multicomponent strategy for stereospecific construction oftricyclic pyrrolo[1,2-a]quinolines'', Chem. Commu., 2012,48, 11966.

     

     

主要获奖：

江苏省教育科学研究成果一等奖（3/4），江苏省教育厅，2016.